Prof. Guido Pampaloni
Associate professor (Professore Associato)
Address : Via G. Moruzzi, 13 – Pisa
Phone : +39 050 2219219
Fax : +39 050 2220673
E-Mail : Questo indirizzo email è protetto dagli spambots. E' necessario abilitare JavaScript per vederlo.
Born 1955, Pontedera (PI) (Italy)
1979 Degree in Chemistry summa cum laude (University of Pisa)
1983 PhD in Chemistry (Scuola Normale Superiore, Pisa)
1992 Permanent position as Associate Professor (University of Pisa)
Research Interests and selected publications
• Reactivity of high valent, early transition metal halides and activation of small molecules
- F. Marchetti, G. Pampaloni, S. Zacchini, A Simple Route to Thermally-Stable Salts of Pyrrolidinium-2-Carbonylchloride, RCS Advance, 4, 60878-60882 (2014)
- S. Dolci, F. Marchetti, G. Pampaloni, S. Zacchini, The Reactivity of Molybdenum Pentachloride with Ester Molecules: Ester Activation, Metal Reduction and Synthesis of 1D Coordination Polymers, Eur. J. Inorg. Chem., 1371-1380 (2013)
- F. Marchetti, G. Pampaloni, “Interaction of niobium and tantalum pentahalides with O-donors: coordination chemistry and activation reactions [Feature Article], Chem. Commun., 48, 635-653 (2012)
- S. Dolci, F. Marchetti, G. Pampaloni, S. Zacchini, C-N Bond Forming Self-Condensation of Amide Promoted by MoCl5 at Room Temperature, Inorg. Chem., 50, 3846-3848 (2011)
• Salts containing unusual organic cations stable at room temperature
- F. Marchetti, G. Pampaloni, C. Pinzino, "Long-lived radical cation salts obtained by interaction of monocyclic arenes with Niobium and Tantalum pentahalides at room temperature: EPR and DFT studies", Chem. Eur. J., 19, 13962-13969 (2013)
- F. Marchetti, G. Pampaloni, S. Zacchini, Lactam/MoCl5 Interaction in CH2Cl2: synthesis and X-ray Characterization of Protonated-Valerolactam Salts, RSC Advances, 3, 10007-10013 (2013)
• Transition metal coordination compounds as catalytic precursors
- M. Hayatifar, G. Pampaloni, L. Bernazzani, C. Capacchione, A. M. Raspolli Galletti, Y. Kissin, A new type of post-metallocene catalyst for alkene polymerization. Copolymerization of ethylene and 1-hexene with titanium complexes bearing N,N-dialkylcarbamato ligands, Polym. Int., 63, 560-567 (2014)
- Fabio Marchetti, Guido Pampaloni, Calogero Pinzino, Filippo Renili, Timo Repo, Sirpa Vuorinen, Ring Opening Polymerization of rac-Lactide by Group 4 Tetracarbamato Complexes: Activation, Propagation and Role of The Metal, Dalton Trans., 42, 2792-2802 (2013)
- F. Masi, A. Sommazzi, G. Pampaloni, F. Renili, A. M. Raspolli Galletti,, M. Polesello, Componente solido di catalizzatore, catalizzatore comprendente detto componente solido e procedimento per la (co)polimerizzazione di alfa-olefine, Domanda MI2010A002401 del 27/12/2010 a nome di Polimeri Europa
Teaching
056CC - Chimica Generale (fondamentale, I anno, II semestre, corso di Laurea di Primo Livello in Fisica)
Registro delle Lezioni
088CC – Chimica Inorganica I (fondamentale, II anno, I semestre, corso di Laurea di Primo Livello in Chimica)
Registro delle Lezioni
257CC – Chimica Nucleare (opzionale, I anno, I semestre, corso di Laurea Specialistica in Chimica)
Registro delle Lezioni