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Supervisors: Prof.ssa Anna Maria Raspolli Galletti, Dott.ssa Claudia Antonetti
Title: Platform-chemicals synthesis through selective hydrogenation of chemical intermediates from renewables
Abstract:
Catalytic conversion of renewables is an important topic today. This is linked to the necessity of replacing fossil resources with renewables ones. In this perspective, 5-hydroxymethyl-2- furaldehyde (HMF) is a fundamental molecule because it could be obtained from renewables resources and through its hydrogenation it is possible to obtain important monomers, such as 2,5- bis(hydroxymethyl)furan (BHMF) and 2,5-bis(hydroxymethyl)tetrahydrofuran (BHMTF), and bio- fuel, such as 2,5-dimethylfuran (DMF). The goal of this project is to optimize the synthesis of these compounds, in respect of Green Chemistry principles, working with heterogeneous catalysts and water as solvent. Furthermore, we’ll investigate two different hydrogenating agents: hydrogen and formic acid, a byproduct of HMF synthesis. Once optimized the synthesis of these compounds, starting from HMF, we’ll study the possibility of using monosaccharides and polysaccharides aqueous solution, obtained from hydrolysis of biomass, as starting materials and the one-pot conversion of biomass. At the end of reactions we’ll study the recyclability of catalysts and their reactivation.
Poster communications at congress:
▪ Authors: Claudia Antonetti, Domenico Licursi, Anna Maria Raspolli Galletti, Erika Ribechini, Sara Fulignati, Martinelli, Mattia Melloni, Fabrizio Cavani
“Sintesi di 5-idrossimetil-2-furaldeide (HMF) da rinnovabili in fase acquosa con catalizzatori acidi eterogenei”
3° Workshop Nazionale GRUPPO INTERDIVISIONALE GREEN CHEMISTRY - CHIMICA SOSTENIBILE, 2015
▪ Authors: Claudia Antonetti, Domenico Licursi, Elisa Bertolucci, Sara Fulignati, Marco Martinelli, Anna Maria Raspolli Galletti
“Heterogeneous catalysis for the production of 5-hydroxymeththyl-2-furfural and of 2,5-bis(hydroxymethyl)furan from fructose and inulin”
XIX Congresso Nazionale della Divisione di Chimica Industriale della Società Chimica Italiana – Materiali e Prodotti per il futuro dell’Industria Chimica, 2015
Oral communications at congress:
▪ Authors: Sara Fulignati, Claudia Antonetti, Domenico Licursi, Marco Martinelli, Anna Maria Raspolli Galletti, Erika Ribechini, Arianna Massaro
“Sustainable synthesis of 5-hydroxymethyl-2-furaldehyde and analytical study of the solid by-products” (awarded as the best flash presentation of the congress)
XIX Congresso del Gruppo Interdivisionale di Catalisi della Società Chimica Italiana, 11-14 Settembre 2016 (Bressanone)
▪ Authors: Claudia Antonetti, Sara Fulignati, Domenico Licursi, Marco Martinelli, Sara Rapiti, Anna Maria Raspolli Galletti
“Della biomassa lignocellulosica non si butta via niente: esempi di valorizzazione integrale di biomasse diverse”
4° Workshop Nazionale GRUPPO INTERDIVISIONALE GREEN CHEMISTRY – CHIMICA SOSTENIBILE, 10 Giugno 2016 (Firenze)
▪ Authors: Sara Fulignati, Claudia Antonetti, Anna Maria Raspolli Galletti, Erika Ribechini
“Catalytic valorisation of renewable resources”
Comunicazione al XIII PhD-Chem Day del CIRCC-Consorzio Interuniversitario Reattività Chimica e Catalisi, 10-11 Marzo 2016 (Bologna)
Journal articles:
▪ C. Antonetti, M. Melloni, D. Licursi, S. Fulignati, E. Ribechini, S. Rivas, J.C. Parajó, F. Cavani, A.M. Raspolli Galletti
“Microwave-assisted dehydration of fructose and inulin to HMF catalyzed by niobium and zirconium phosphate catalysts” Appl. Catal. B: Env., 2017, 206, 364-377. doi:10.1016/j.apcatb.2017.01.056
▪ C. Antonetti, D. Licursi, S. Fulignati, G. Valentini, A.M. Raspolli Galletti
“New frontiers in the catalytic synthesis of levulinic acid: from sugars to raw and waste biomass as starting feedstock”, Catalysts, 2016, 6, 196-224. doi:10.3390/catal6120196